Methyl 2-Methyl Butyrate
CAS: 868-57-5
TopFruity
Identifiers
Manufacturer
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CAS number
868-57-5
CAS (all sources)
868-57-5
CAS (Perfumiarz)
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CAS (PerfumersWorld)
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CAS (FraterWork)
868-57-5
CAS (EU Hekserij)
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CAS (TSCA Hekserij)
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INCI name (FraterWork)
METHYL 2-METHYLBUTANOATE
IUPAC name (FraterWork)
methyl 2-methylbutanoate
INCI (Hekserij)
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EC number (Hekserij)
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FEMA (Hekserij)
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UN number
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Synonyms (PerfumersWorld)
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Synonyms (FraterWork)
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Scent profile
Note type (FraterWork)
Top Note
Odour family (FraterWork)
Fruity
Odour profile (FraterWork)
Methyl 2-Methylbutyrate delivers a bright, ethereal green apple
aroma with fresh, ripe, and pulpy fruit character, enhanced by powerful lift and
juicy brightness alongside subtle powdery, fatty, and lily-of-the-valley
undertones.
Appearance (FraterWork)
Colourless liquid
Descriptions
Comment (FraterWork)
This remarkable ester opens with an immediately recognisable burst of fresh
green apple that captures that crisp, first-bite sensation. Its ethereal quality
provides tremendous volatility and lift, creating a sparkling opening that
radiates from the skin. Unlike heavier fruit materials, it delivers clean
brightness without weight or density.
Your formulations benefit from its exceptional potency—detectable at just 0.92
parts per billion. This extreme sensitivity means tiny additions create massive
impact, making it invaluable for boosting the perceived freshness of fruit
accords. The material's unique ability to bridge fruity and floral territories
stems from its subtle lily-of-the-valley undertones, allowing seamless
integration into white floral compositions.
Use it strategically as a brightness catalyst rather than a dominant note. Its
fleeting nature makes it perfect for creating dynamic fragrance openings that
quickly recede to reveal heart materials. Combine with Ethyl 2-Methylbutyrate
for fuller apple effects, or blend with cis-3-Hexenol for authentic Granny Smith
apple accords. Its natural occurrence across numerous fruits validates its role
in creating realistic, mouth-watering effects.
METHYL 2-METHYL VS ETHYL 2-METHYL
The fundamental difference lies in the alcohol portion of these esters. Methyl
2-Methylbutyrate uses methanol as its alcohol component (C6H12O2, MW 116.16),
while Ethyl 2-Methylbutyrate uses ethanol (C7H14O2, MW 130.18). This seemingly
small structural change creates significant performance differences. The methyl
version is more volatile with a lower boiling point (115°C vs 130°C), making it
extremely fleeting and ethereal. The ethyl version lasts longer and delivers
more powerful, diffusive impact. Olfactively, Methyl 2-Methylbutyrate provides a
crisp green apple sparkle that flashes off quickly, perfect for creating
momentary brightness. Ethyl 2-Methylbutyrate offers a broader, sweeter red
apple-to-tropical fruit profile with greater staying power and radiance. Choose
the methyl version when you need pure ethereal lift without commitment to a
fruity theme. Select the ethyl version when you want substantial fruity body in
your top notes that bridges into the heart composition.
aromachem Best Seller
Notes
This remarkable ester opens with an immediately recognisable burst of fresh
green apple that captures that crisp, first-bite sensation. Its ethereal quality
provides tremendous volatility and lift, creating a sparkling opening that
radiates from the skin. Unlike heavier fruit materials, it delivers clean
brightness without weight or density.
Your formulations benefit from its exceptional potency—detectable at just 0.92
parts per billion. This extreme sensitivity means tiny additions create massive
impact, making it invaluable for boosting the perceived freshness of fruit
accords. The material's unique ability to bridge fruity and floral territories
stems from its subtle lily-of-the-valley undertones, allowing seamless
integration into white floral compositions.
Use it strategically as a brightness catalyst rather than a dominant note. Its
fleeting nature makes it perfect for creating dynamic fragrance openings that
quickly recede to reveal heart materials. Combine with Ethyl 2-Methylbutyrate
for fuller apple effects, or blend with cis-3-Hexenol for authentic Granny Smith
apple accords. Its natural occurrence across numerous fruits validates its role
in creating realistic, mouth-watering effects.
METHYL 2-METHYL VS ETHYL 2-METHYL
The fundamental difference lies in the alcohol portion of these esters. Methyl
2-Methylbutyrate uses methanol as its alcohol component (C6H12O2, MW 116.16),
while Ethyl 2-Methylbutyrate uses ethanol (C7H14O2, MW 130.18). This seemingly
small structural change creates significant performance differences. The methyl
version is more volatile with a lower boiling point (115°C vs 130°C), making it
extremely fleeting and ethereal. The ethyl version lasts longer and delivers
more powerful, diffusive impact. Olfactively, Methyl 2-Methylbutyrate provides a
crisp green apple sparkle that flashes off quickly, perfect for creating
momentary brightness. Ethyl 2-Methylbutyrate offers a broader, sweeter red
apple-to-tropical fruit profile with greater staying power and radiance. Choose
the methyl version when you need pure ethereal lift without commitment to a
fruity theme. Select the ethyl version when you want substantial fruity body in
your top notes that bridges into the heart composition.
aromachem Best Seller
Usage
Average use (FraterWork)
0.89% in a perfume compound
Uses (FraterWork)
Essential top-note modifier providing ethereal lift, creates realistic
apple-strawberry accords, adds juicy brightness to compositions.
IFRA 51 (FraterWork)
Details coming soon…
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